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71.
Phenolic compounds in olive oil mill wastewaters were analysed by HRGC–MS after extracting the acidified solution with ethyl acetate and derivatization with N,O-bis(trimethylsilyl)trifluoroacetamide. Both simple and complex phenols were detected with the latter being the most abundant. 1,2-dihydroxybenzene (catechol), p-hydroxyphenyl ethanol (tyrosol), 3,4-dihydroxyphenyl ethanol (hydroxytyrosol) and 4-hydroxy-3-methoxyphenyl ethanol (homovanillyl alcohol) predominated among the simple phenols using a gas chromatograph coupled with a mass selective detector. 相似文献
72.
Distribution and availability of potentially toxic metals in soil in central area of Belgrade,Serbia 总被引:1,自引:0,他引:1
Rabia Ahmed Ghariani Ivan Gržetić Mališa Antić Snežana Nikolić Mandić 《Environmental Chemistry Letters》2010,8(3):261-269
Belgrade, capital city of Serbia, has over 1,600,000 inhabitants and over 400,000 vehicles trafficking every day on its streets.
The investigation of soil pollution was performed by sequential extraction analysis to investigate the availability of potentially
toxic metals (Zn, Cd, Pb, Co, Ni, Cu, Cr and Mn) under different oxidation and pH conditions. All investigated metals were
mainly extracted from soils with neutral or acidic extractants. Serious pollution was observed along roads and streets with
high traffic frequency, but Pb and Ni pollution was the highest since their concentrations exceed both soil Serbian standard
and Canadian guidance values and is characteristic for all investigated sites. Cd, Cu, Cr and Zn concentrations are moderately
high since they are between Canadian guideline and Serbian standard. 相似文献
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Iyad Ahmed Abboud 《Environmental geochemistry and health》2018,40(4):1405-1435
Quality of groundwater in the Yarmouk basin, Jordan has been assessed through the study of hydrogeochemical characteristics and the water chemistry as it is considered the main source for drinking and agriculture activities in the region. The results of the relationship between Ca2+ + Mg2+ versus HCO3? + CO32?, Ca2+ + Mg2+ versus total cations, Na+ + K+ versus total cations, Cl? + SO42? versus Na+ + K+, Na+ versus Cl?, Na+ versus HCO3? + CO32?, Na+ versus Ca2+, and Na+: Cl? versus EC describe the mineral dissolution mechanism through the strong relationship between water with rocks in alkaline conditions with the release of Ca2+, Mg2+, Na+, K+, HCO3?, CO32?, SO42?, and F? ions in the groundwater for enrichment. Furthermore, evaporation processes, groundwater depletion, and ion exchange contribute to the increased concentration of Na+ and Cl? ions in groundwater. Anthropogenic sources are one of the main reasons for contamination of groundwater in the study area and for increasing the concentration of Mg2+, Na+, Cl?, SO42?, and NO3? ions. Results show the quality of groundwater in the study area is categorized as follows: HCO3? + CO32? > Cl? > SO42? > NO3? > F? and Na+ > Ca2+ > Mg2+ > K+. In conclusion, the results of TDS, TH, and chemical composition showed that 26% of the groundwater samples were unsuitable for drinking. About 28% of groundwater samples in the study area have a high concentration of Mg2+, Na+, and NO3? above the acceptable limit. Also, based on high SAR, 10% of the groundwater samples were not suitable for irrigation purposes. 相似文献
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Dissolution of raw phosphate (apatite) in sea water of the Gulf of Aqaba was investigated through lab incubation experiments. Three types from three different sources (Al-Hasa, Al-Abyad and Esh-Shydiya) have been used for these experiments. Impact of quantity, grain size, and source (type) of raw phosphate on dissolution rate were studied. Statistical analysis shows significant differences between the results obtained from comparing each two weights; as weight of apatite increased, dissolved inorganic phosphate-phosphorus (DIP) and fluoride in sea water solution increased. The differences between the dissolution rates of raw phosphate from the three sites were not significant while the differences between the different grain size fractions were significant. Dissolution rates were inversely related to particle size. Using a worst-case scenario, a conservative estimate of the maximum increase in DIP in seawater of the Gulf of Aqaba due to the apatite particles lost to the sea during ship loading resulted in DIP concentrations of 0.03 μM per year. As the residence time of the water in the Gulf of Aqaba is about one year, the DIP concentration will not increase by more than 0.03 μM under the estimated annual quantity of exported phosphate. Fluoride will not increase by more than 0.03 mg/l under the same conditions. 相似文献
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Alireza A. Shamshirsaz Kelsey A. Stewart Hadi Erfani Ahmed A. Nassr Nathan C. Sundgren Amy R. Mehollin-Ray Shaine A. Morris Jimmy Espinoza Magdalena Sanz Cortes Christopher Cassady Timothy C. Lee Eumenia C. Castro Olutoyin A. Olutoye Deepak K. Mehta Darrell Cass Oluyinka O. Olutoye Michael A. Belfort 《黑龙江环境通报》2019,39(4):287-292
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